Bioactive Rearrangement Products from Aqueous Photolysis of Pharmaceutical Steroids
نویسندگان
چکیده
منابع مشابه
Products from the photolysis of diazoacetyl chymotrypsin.
1. A new and convenient synthesis of p-nitrophenyl diazoacetate has been devised from p-nitrophenyl chloroformate and diazomethane. 2. p-Nitrophenyl diazoacetate reacts stoichiometrically with chymotrypsin to yield diazoacetyl chymotrypsin. 3. Photolysis of the diazoacetyl enzyme with light of wave length greater than 320 rnp yields a mixture of (a) glycolic acid and regenerated chymotrypsin an...
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ژورنال
عنوان ژورنال: Organic Letters
سال: 2019
ISSN: 1523-7060,1523-7052
DOI: 10.1021/acs.orglett.9b00972